Document Type

Article

Date of Original Version

2015

Abstract

We consider linear arrays of cells of volume Vc populated by monodisperse rods of size σVc, σ = 1,2, . . ., subject to hardcore exclusion interaction. Each rod experiences a position-dependent external potential. In one application we also examine effects of contact forces between rods. We employ two distinct methods of exact analysis with complementary strengths and different limits of spatial resolution to calculate profiles of pressure and density on mesoscopic and microscopic length scales at thermal equilibrium. One method uses density functionals and the other statistically interacting vacancy particles. The applications worked out include gravity, power-law traps, and hard walls. We identify oscillations in the profiles on a microscopic length scale and show how they are systematically averaged out on a well-defined mesoscopic length scale to establish full consistency between the two approaches. The continuum limit, realized as Vc → 0, σ →∞ at nonzero and finite σVc, connects our highest-resolution results with known exact results for monodisperse rods in a continuum. We also compare the pressure profiles obtained from density functionals with the average microscopic pressure profiles derived from the pair distribution function.

Creative Commons License

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.

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