The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions

Authors

Esther Zeigerson, Ben-Gurion University of the Negev
Gregory Ginzburg, Ben-Gurion University of the Negev
Louis J. Kirschenbaum, University of Rhode Island
Dan Meyerstein, Ben-Gurion University of the Negev

Document Type

Article

Date of Original Version

10-9-1981

Abstract

The electrochemical oxidation of three divalent nickel complexes with tetra-aza-macrocyclic ligands in perchlorate- and sulphate-containing aqueous solutions is reported. The mechanism of oxidation is analysed in detail. Redox potentials, diffusion coefficients, a transfer coefficient and a heterogeneous rate constant are reported. The pH effect on the electrochemical oxidations is discussed. © 1981 Elsevier Sequoia S.A.

Publication Title, e.g., Journal

Journal of Electroanalytical Chemistry

Volume

127

Issue

1-3

Citation/Publisher Attribution

Zeigerson, Esther, Gregory Ginzburg, Louis J. Kirschenbaum, and Dan Meyerstein. "The electrochemical oxidation of divalent nickel complexes with tetra-aza-macrocyclic ligands in aqueous solutions." Journal of Electroanalytical Chemistry 127, 1-3 (1981). doi: 10.1016/S0022-0728(81)80472-X.