Thermal reactions of LiP F6 with added LiBOB
Document Type
Article
Date of Original Version
9-13-2007
Abstract
The effect of thermal storage on 1.0 M LiP F6 in 1:1:1 ethylene carbonate/dimethyl carbonate/diethyl carbonate with 5 wt % added lithium bisoxalatoborate [LiB (C2 O4) 2 LiBOB] was investigated. Thermal storage of LiP F6 initiates disproportionation reactions of LiBOB, which generate LiB F4, lithium difluorooxalatoborate [LiB F2 (C2 O4), Li F2 OB], and lithium tetrafluorooxolatophosphate [LiP F4 (C2 O4), Li F4 OP]. The synthesis and characterization of Li F4 OP are presented along with a preliminary electrochemical investigation of Li F4 OP -based electrolytes. © 2007 The Electrochemical Society.
Publication Title, e.g., Journal
Electrochemical and Solid-State Letters
Volume
10
Issue
11
Citation/Publisher Attribution
Xiao, Ang, Li Yang, and Brett L. Lucht. "Thermal reactions of LiP F6 with added LiBOB." Electrochemical and Solid-State Letters 10, 11 (2007): 241-244. doi: 10.1149/1.2772084.
