Preparation of diarylamines by the addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes
Document Type
Article
Date of Original Version
9-29-2003
Abstract
The addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes in THF (-78°C) affords the corresponding diarylamines in one-pot and the reaction appears to be general in scope. A 'nitroso'-based mechanism is proposed for this novel nitroreductive N-arylation reaction. © 2003 Elsevier Ltd. All rights reserved.
Publication Title, e.g., Journal
Tetrahedron Letters
Volume
44
Issue
40
Citation/Publisher Attribution
Yang, Tianle, and Bongsup P. Cho. "Preparation of diarylamines by the addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes." Tetrahedron Letters 44, 40 (2003): 7549-7552. doi: 10.1016/j.tetlet.2003.07.002.
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