Document Type

Article

Date of Original Version

1987

Abstract

Since the Heisenberg spin chain can be considered the simplest realistic model of magnetism, surprise and some degree of controversy have resulted from recent work of Haldane. The prediction is that quantum spin chains with h a l fi n t e g e r spin should all display T=0 phase behavior equivalent to that of the Bethe Ansatz integrable (solvable) spin‐1/2 quantum chain. More remarkably, the class of i n t e g e rspin chains is predicted to show very different phase behavior. In particular, a gap should be present in the spectrum of a Heisenberg antiferromagnetic chain. This remarkable feature is counterintuitive in terms of accepted wisdom in magnetism (spin‐wave theory, spin‐Peierls theory) and critical phenomena. Consequently the vertification of the prediction is of great interest. A considerable amount of numerical work has been done, involving finite‐chain, finite‐size scaling, variational, Monte Carlo and other calculations, which will be reviewed here. The present consensus is that the weight of numerical evidence supports the prediction, although puzzling features still remain. Adding additional interactions to the basic Heisenberg Hamiltonian such as spin (X X Z) anisotropy, single‐ion anisotropy, biquadratic exchange, and an applied magnetic field, generates a rich and complicated phase diagram for chains with spin >1/2, particularly for the case of integer spin. The s=1 phase diagram seems to display critical behavior of a type not previously encountered. A theoretical appraisal of the Haldane phenomenon will include a discussion of the possible role of nonintegrability. Mention will also be made of current progress in experimental investigation of the phenomenon, including problems that might be encountered. More recent work of Affleck has greatly generalized the field‐theoretic mappings which underlay the original work of Haldane. A number of interesting problems have been mapped into quantum spin chains of various types, including field theoretic phenomena and the localization problem of the quantum Hall effect.

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