Date of Award

2019

Degree Type

Dissertation

Degree Name

Doctor of Philosophy in Chemistry

Department

Chemistry

First Advisor

Jimmie C. Oxley

Abstract

As seen in multiple cases, including the 2013 Boston Marathon bombing, improvised explosives compositions may be as simple as a combination commonly-available fuel/oxidizer (FOX) mixtures initiated by an electrically-heated wire. The predictive knowledge of large scale explosive potential of FOX mixtures is incomplete. Predicting explosive potential from laboratory-scale analytical test data is desirable. Herein the explosive properties of fuel/oxidizer combinations (FOX) were measured at both the small scale (2 g) with bomb calorimetry for heat output and closed-vessel dynamic pressure rise and also on the large scale (5 kg) with high speed photography for detonation velocity and with piezoelectric pressure probes for TNT air blast equivalence. Potassium nitrate (KN), potassium chlorate (KC), potassium permanganate (KMnO4), potassium iodate (KIO3), ammonium nitrate (AN), and ammonium perchlorate (AP) were prepared with sucrose (Su) fuel, and KN, AP, and AN were prepared with aluminum (Al) fuel. The results were compared to each other as well as predictions from Cheetah thermochemical code in order to correlate detonation performance, particularly the ideality of detonation performance, with simple laboratory screening tests.

Presented here are the results of around 60 explosive experiments which have become the first series of experiments at the URI explosives test facility to successfully field photon Doppler velocimetry (PDV) and ultra-high speed photography. The experiments outlined herein focus on homogeneous improvised explosives, namely hydrogen peroxide (HP) aqueous solutions fueled with ethanol (EtOH). These materials have been chosen as a template system for evaluation with time-resolved detonation diagnostics aimed at screening clandestine non-ideal explosive threat materials for detonable character even, and especially, in configurations below their critical diameter. The ‘galloping’ detonation instabilities of these materials have been captured on camera in the stoichiometric mixture of HP:EtOH in diameters from 1 to 2.6 inches; a steady detonation never formed. Reactive particle velocity waveforms for this mixture were measured by PDV through a PMMA pressure-maintaining window. These materials were subjected to both overdriven and underdriven configurations, and non-steady waveforms have been collected to monitor non-ideal explosives under these conditions i.e. inside the infinite diameter region of a range of different shock loading environments. Several mixtures of HP:EtOH have also been artificially doped with glass microballoons to study the ideality of this mixture in a heterogeneous regime. Successful detonations of heterogeneous HP:EtOH mixtures were observed using as low as 40% HP.

Available for download on Saturday, January 23, 2021

Share

COinS