Date of Original Version
Reported herein is the use of γ-cyclodextrin for two tandem functions: (a) the extraction of carcinogenic polycyclic aromatic hydrocarbons (PAHs) from oil samples into aqueous solution, and (b) the promotion of highly efficient energy transfer from the newly extracted PAHs to a high-quantum yield fluorophore. The extraction proceeded in moderate to good efficiencies, and the resulting cyclodextrin-promoted energy transfer lead to a new, brightly fluorescent signal in the aqueous solution. The resulting dual-function system (extraction followed by energy transfer) has significant relevance in the environmental detection and cleanup of oil spill-related carcinogens.
Serio, N., Chanthalyma, C., Prignano, L., & Levine, M. (2013). Cyclodextrin-Enhanced Extraction and Energy Transfer of Carcinogens in Complex Oil Environments. ACS Applied Materials & Interfaces, 5(22), 11951–11957. doi: 10.1021/am403702n
Available at: http://dx.doi.org/10.1021/am403702n