Date of Original Version
In 1896, Arrhenius provided the first roughly quantitative sense of the plausible magnitude of human-induced changes in the concentration of CO2 in the atmosphere. Since then, all chemists could be aware that increasing CO2 in the atmosphere must lead to increasing amounts in the ocean and a corresponding increase in acidity. For a long time, however, no one appears to have thought much about this latter consequence, probably because the likely effects were small and were, in any case, rather troublesome to calculate. It was only in 1909 that Sørensen proposed the concept of the pH scale. The negligible level of concern about the effect of CO2 on Earth's heat balance was not much affected by the work of Callendar (1938), who argued that the increasing concentrations in the atmosphere could be observed and would be significant. The radiative balance calculations of Plass (1956), published in Tellus, began to influence those who read such journals, and the beginnings of the Keeling curve brought widespread attention to the increasing atmospheric CO2 concentration.
Michael E.Q. Pilson. (2014). "Changing pH in the Surface Ocean." Oceanography, 27(1), 120-125. Available at: http://dx.doi.org/10.5670/oceanog.2014.15